Hi @Anonymous User
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@Anonymous User @Andy
You know, it's highly unlikely that Now TV will roll out a new app for the PS 3, in ROI, at this late stage in the PS 3's life cycle. IT companies do not like to write new software for old hardware, especially if the OEM no longer supports that device, in this case SONY.
However, as I do not own a PlayStation I do not actually know if Sony still supports the PS3, i.e. with software updates, maintenance releases and new software, but as the PS4 has been out for sometime, it's a good guess that they probably don't.
Still, I could be wrong.